Effect of Substituents on Basicity – Pedagogy Zone
Presence of electron releasing groups on the benzene ring of aromatic amines enhances the electron density on nitrogen, thus increase the basicity. On the contrary, presence of electron withdrawing groups reduces the basicity of amines. Presence of −NO2 group indicates −I and −R effect, thus enhancing the delocalization of lone pair on nitrogen with π-electrons of the benzene ring system
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